Nuclear Magnetic Resonance Coherence Transfer in a Homonuclear Two Spin - 1 / 2 Solid - State System
نویسندگان
چکیده
.........................................................................................23 Introduction....................................................................................24 Theory............................................................................................25 Results and Discussion...................................................................32 Conclusions ....................................................................................46 Acknowledgements ........................................................................47 4. DIPOLAR-COUPLING-MEDIATED COHERENCE TRANSFER IN AN UNORIENTED HOMONUCLEAR TWO SPIN-1⁄2 SOLID STATE SYSTEM.........................................................................48 Abstract ..........................................................................................48 Introduction....................................................................................49 Theory of the Static Dipolar Hamiltonian......................................50 Methods..........................................................................................52 Results and Discussion...................................................................54 Unoriented Sample Simulation for HD...............................54 The DRAMA Experiment ..................................................73 The DRAWS Experiment...................................................84 The RFDR Experiment.......................................................91.........................................................................................48 Introduction....................................................................................49 Theory of the Static Dipolar Hamiltonian......................................50 Methods..........................................................................................52 Results and Discussion...................................................................54 Unoriented Sample Simulation for HD...............................54 The DRAMA Experiment ..................................................73 The DRAWS Experiment...................................................84 The RFDR Experiment.......................................................91
منابع مشابه
Analysis of dipolar-coupling-mediated coherence transfer in a homonuclear two spin-12 solid-state system
Homonuclear dipolar-mediated coherence transfer (DCT), a through-space transfer of magnetization between like spins, can yield otherwise difficult-to-obtain structural information for macromolecules by measuring the internuclear distances between two sites of interest. The behavior of a spin-12 system under DCT is analyzed in detail by computing the time development of the density matrix using ...
متن کاملDipolar-coupling-mediated Coherence Transfer in a Homonuclear Two Spin 1⁄2 Solid State System
Homonuclear dipolar-mediated coherence transfer (DCT), a through-space transfer of magnetization between like spins, can yield otherwise difficult-to-obtain structural information for macromolecules by measuring the internuclear distances between two sites of interest. The behavior of a spin-1⁄2 system under DCT is analyzed in detail by computing the time development of the density matrix using...
متن کاملDipolar Recoupling and Decoupling
In solid state nuclear magnetic resonance spectroscopy, the magic angle spinning technique is often used to remove anisotropic interactions and generate high resolution spectra. However, these interactions contain valuable information about molecular structure and dynamics. In particular, the dipole-dipole coupling strength between two spin-1/2 nuclei is a direct reflection of their interatomic...
متن کاملDipolar Coherence Transfer in the Presence of Chemical Shift for Unoriented and Oriented Homonuclear Two Spin-1⁄2 Solid State Systems
متن کامل
Distance Measurements in Multiply Labeled Crystalline Cytidines by Dipolar Recoupling Solid State NMR
To systematically explore the effects of spin system size and geometry on the precision and accuracy of two-dimensional solid state NMR distance measurements, we have applied two homonuclear dipolar recoupling experiments, 2D DRAWS and 2D RFDR, to five polycrystalline samples of uniformly or selectively 13Clabeled cytidine. Distance information has been obtained from the intensities and time be...
متن کامل